Optimization and Removal of Heavy Metals from Groundwater Using Moringa Extracts and Coconut Shell Carbon Powder

  • Tayi Preethi Rangamani Department of Freshman Engineering, PVP Siddhartha Institute of Technology, Kanuru, Vijayawada, Andhra Pradesh, India http://orcid.org/0009-0002-0428-9297
  • Mudigeti Srinivasulu Department of Basic Humanities and Sciences, Seshadri Rao Gudlavalleru Engineering College, Gudlavalleru, Andhra Pradesh, India http://orcid.org/0009-0002-0428-9297
  • Gogula Sreedevi Department of Freshman Engineering, PVP Siddhartha Institute of Technology, Kanuru, Vijayawada, Andhra Pradesh, India https://orcid.org/0000-0002-7544-1498
  • Tanuku Srinivas Department of Civil Engineering, GITAM School of Technology, GITAM (Deemed to be University), Visakhapatnam, Andhra Pradesh, India
Keywords: Carbon from coconut shells, Heavy metals, Moringa olifera leaves powder, Moringa olifera Seeds powder, Optimization

Abstract

This study focuses on enhancing the efficacy and elimination of heavy metals from groundwater by employing bio-absorbents generated from Moringa extracts and Coconut shell carbon powder. The green synthesis technique was utilized to produce cost-effective absorbents, including powdered Moringa seeds, leaves and carbon from coconut shells. The study examines the effectiveness of synthetic bio-absorbents in removing heavy metals, including Copper (Cu), Cadmium (Cd), Iron (Fe), Lead (Pb), Chromium (Cr), and Zinc (Zn), from groundwater. Identifying functional groups such as Hydroxyl (OH), C-H of alkenes, C=C of alkenes, and C-O from carboxylic acids have been determined to be essential for removing metals in groundwater. The method of FT-IR spectroscopy was used to characterize these functional groups. The examination of the morphology of Moringa seeds indicated the presence of consistent spherical network sheets, but Moringa leaves had a hexagonal network structure like a flower. The coconut shell photos revealed the presence of irregular, small-sized flakes that were clustered together to create a sheet. In light of the escalating deterioration of groundwater quality in Vijayawada as a result of industrial expansion, urban development, and significant infrastructure initiatives, the primary objective of the study was to ascertain the primary contaminants present in the groundwater. Subsequently, adsorption methods utilizing natural bio-absorbents were employed. Water samples were gathered and exposed to bio-absorption utilizing powdered Moringa olifera leaves, powdered Moringa olifera seeds, and powdered carbon derived from coconut shells. The technique of Atomic Absorption Spectroscopy was utilized to examine the decrease in concentrations of heavy metals. The findings demonstrated that the bio-absorption of heavy metals was more prominent in Moringa olifera seed powder than in Moringa olifera leaf powder and coconut shell carbon powder. The highest levels of adsorption for copper, cadmium, and lead were achieved at 98.5%, 99.5% and 99.4%, respectively. This work offers useful insights into the potential of bio-absorbents manufactured using green methods for effectively eliminating heavy metals from groundwater. It addresses the crucial problem of water quality in metropolitan areas.

References

Ali, E. N., & Seng, H. T. (2018). Heavy metals (Fe, Cu, and Cr) removal from wastewater by Moringa oleifera press cake. MATEC Web of Conferences, 150, 02008, MUCET, EDP Sciences. https://doi.org/10.1051/matecconf/201815002008

Alinnor, I. J. (2007). Adsorption of heavy metal ions from aqueous solution by fly ash. Fuel, 86(5-6), 853–857.

Amin, N. M., Kaneco, S., Kitagawa, T., Begum, A., Katsumata, H., Suzuki, T., & Ohta, K. (2006). Removal of arsenic in aqueous solutions by adsorption onto waste rice husk. Indian Journal of Environmental Protection, 45(24), 8105–8110. https://doi.org/10.1021/ie060344j

Araujo, C. S. T., Carvalho, D. C., Rezende, et al. (2013). Bioremediation of waters contaminated with heavy metals using Moringa oleifera seeds as biosorbent. In: Applied Bioremediation – Active and Passive Approaches (PatilY., ed.). In Tech., pp. 249-255. https://doi.org/10.5772/56157

Aziz, N., Jayasuriya, & Fan, N. L. (2016). Adsorption study on Moringa oleifera seeds and Musa cavendish as natural water purification agents for removal of Lead, Nickel and Cadmium from drinking water. Mat Sci Eng., 136, 1–9. https://doi.org/10.1088/1757-899X/136/1/012044

Bansal, M., Singh, D., & Garg, V. K. (2009). A comparative study for the removal of hexavalent chromium from aqueous solution by agriculture wastes’ carbons. Journal of Hazardous Materials, 171(1–3), 83–92. https://doi.org/10.1016/j.jhazmat.2009.05.124.

BIS (2013). <https://www.bis.gov.in/qazwsx/cmd/water_manual_final.pdf>

Chanand, B. K. C., & Dudeney, A. W. L. (2008). Reverse osmosis removal of arsenic residues from bioleaching of refractory gold concentrates. Minerals Engineering, 21(4), 272–278.

Cho, H., Oh, D., & Kim, K. (2005). A study on removal characteristics of heavy metals from aqueous solution by fly ash. Journal of Hazardous Materials, 127(1–3),187–195.

Dabrowski, A., Hubicki, Z., Podko´scielny, P., & Robens, E. (2004). Selective removal of the heavy metal ions from waters and industrial wastewaters by ion-exchange method. Chemosphere, 56(2), 91–106.

El Nemr, A., Khaled, A., Abdelwahab, O., & El-Sikaily, A. (2008). Treatment of wastewater containing toxic chromium using new activated Carbon developed from date palm. Journal of Hazardous Material, 152(1), 263–7. https://doi.org/10.1016/j.jhazmat.2007.06.091

FASSI. <https://fssai.gov.in/upload/uploadfiles/files/Manual_Water_Analysis_09_01_2017.>

Fu, F., & Wang, Q. (2011). Removal of heavy metal ions from waste waters: A review. Journal of Environmental Management, 92 (3), 407-418. https://doi.org/10.1016/j.jenvman.2010.11.011.

Ghafar, F., Mohtar, A., Sapawe, N., Hadi, N.N., & Salleh, M.R.M. (2017). Chemically modified Moringa oleifera seed husks as low cost adsorbent for removal of copper from aqueous solution. AIP Conference Proceedings, AIP Publishing LLC. https://doi.org/10.1063/1.5010524

Maina, I. W., Obuseng, & V., & Nareetsile, F. (2016). Use of Moringa oleifera (Moringa) seed pods and Sclerocarya birrea (Morula) nut shells for removal of heavy metals from wastewater and borehole water. J. Chem., 2016. https://doi.org/10.1155/2016/9312952.

Mohan, D., & Pittman, C. U. (2007). Arsenic removal from water/wastewater using adsorbents-A critical review. Journal of Hazardous Materials, 142(1–2), 1-53. https://doi.org/10.1016/j.jhazmat.2007.01.006

Peleka, E. N., & Matis, K. A. (2008). Application of flotation as a pretreatment process during desalination. Desalination, 222(1–3), 1–8.

Qdaisand, H. A., & Moussa, H. (2004). Removal of heavy metals from wastewater by membrane processes: a comparative study. Desalination, 164(2), 105–110.

Sadegh, H., Mazloumbilandi, M., & Chahardouri, M. (2017). Low-cost materials with adsorption performance. Handbook of ecomaterials, pp. 1-33. https://doi.org/10.1007/978-3-319-68255-6_175

Ternes, T. A. (1998). Occurrence of drugs in German sewage treatment plants and rivers. Water Research, 32(11), 3245–3260.

Wang, S., & Wu, H. (2006). Environmental-benign utilization of fly ash as low-cost adsorbents, Journal of Hazardous Materials, 136(3), 482–501. https://doi.org/10.1016/j.jhazmat.2006.01.067

Published
2023-12-30
How to Cite
Rangamani, T. P., Srinivasulu, M., Sreedevi, G., & Srinivas, T. (2023). Optimization and Removal of Heavy Metals from Groundwater Using Moringa Extracts and Coconut Shell Carbon Powder. International Journal of Experimental Research and Review, 36, 89-98. https://doi.org/10.52756/ijerr.2023.v36.008
Section
Articles